Netupitant API Manufacturer in India

Swapnroop Pharma · WHO-GMP Certified · +91 87670 62101

Netupitant API

Netupitant is a synthetic neurokinin-1 (NK1) receptor antagonist and pharmaceutical active pharmaceutical ingredient (API). It is an orally active antiemetic molecule that blocks the action of substance P at NK1 receptors.

Netupitant is used in combination with palonosetron hydrochloride in pharmaceutical formulations for the prevention of acute and delayed chemotherapy-induced nausea and vomiting (CINV). PubChem and IUPHAR/BPS identify Netupitant as an approved NK1 receptor antagonist and antiemetic.

Netupitant API Manufacturer in India

Netupitant is a specialized antiemetic pharmaceutical API relevant to oncology supportive care, chemotherapy-induced nausea and vomiting research, NK1 receptor antagonist development and pharmaceutical formulation.

The EMA assessment report confirms that the active-substance specification for Netupitant includes appearance, IR and HPLC identification, HPLC assay, HPLC impurities, residual solvents, water content, heavy metals, sulfated ash and particle-size distribution.

Chemical Information

CAS Number: 290297-26-6

Molecular Formula: C₃₀H₃₂F₆N₄O

Molecular Weight: 578.59 g/mol

IUPAC Name: 2-[3,5-bis(trifluoromethyl)phenyl]-N,2-dimethyl-N-[4-(2-methylphenyl)-6-(4-methylpiperazin-1-yl)pyridin-3-yl]propanamide

Development Code: Ro 67-3189 / Ro-67-3189

Drug Class: Neurokinin-1 Receptor Antagonist

Therapeutic Class: Antiemetic

Therapeutic Area: Oncology Supportive Care / Gastroenterology

Molecule Type: Synthetic Small Molecule

Stereochemistry: Achiral

PubChem and FDA's Global Substance Registration System confirm the CAS number, molecular formula, molecular weight and achiral nature of Netupitant.

Mechanism of Action

Netupitant is a selective NK1 receptor antagonist.

Its pharmacological activity includes:

  • Blocking neurokinin-1 receptors
  • Inhibiting substance P-mediated signaling
  • Suppressing emetic signaling pathways
  • Reducing chemotherapy-induced nausea
  • Reducing chemotherapy-induced vomiting
  • Contributing to prevention of both acute and delayed CINV

Netupitant's NK1 receptor antagonism is particularly important in controlling the delayed phase of chemotherapy-induced emesis.

Pharmaceutical Applications

Netupitant API is relevant to:

  • Antiemetic pharmaceutical formulations
  • Chemotherapy-induced nausea and vomiting prevention
  • NK1 receptor antagonist research
  • Oncology supportive-care medicines
  • Pharmaceutical formulation development
  • Antiemetic drug development
  • Neurokinin receptor research
  • Pharmaceutical API manufacturing
  • Analytical quality control
  • Pharmaceutical research and development

Chemotherapy-Induced Nausea and Vomiting

Netupitant is used as part of an antiemetic combination with palonosetron, a 5-HT3 receptor antagonist.

The combination targets complementary pathways involved in chemotherapy-induced emesis and is used for prevention of acute and delayed nausea and vomiting associated with cancer chemotherapy.

NK1 Receptor Antagonist

The NK1 receptor is activated by substance P, a neuropeptide involved in the emetic response.

Netupitant selectively antagonizes NK1 receptors and therefore prevents substance-P-mediated signaling associated with chemotherapy-induced vomiting.

Physical Characteristics

Netupitant is a synthetic organic compound with molecular formula C₃₀H₃₂F₆N₄O and molecular weight 578.59 g/mol. FDA's substance database classifies it as an achiral chemical substance with no defined stereocenters.

PubChem reports a calculated XLogP3-AA value of 6.8 and topological polar surface area of 39.7 Ų.

Published laboratory data describe Netupitant as a solid with a melting point around 160–161°C; however, this should not automatically be treated as an official pharmaceutical API release specification.

Solubility

Netupitant is insoluble in water. A laboratory supplier's technical data reports solubility in ethanol and DMSO, while another analytical source reports slight solubility in chloroform, DMSO and methanol. These are useful physicochemical references but should not be confused with a pharmaceutical release specification.

Manufacturing Process

A controlled Netupitant API manufacturing process may involve:

  1. Qualification of starting materials
  2. Preparation of substituted pyridine intermediates
  3. Preparation of substituted aromatic intermediates
  4. Controlled amide formation
  5. Introduction of the bis(trifluoromethyl)phenyl group
  6. Incorporation of the methylpiperazine functionality
  7. Reaction monitoring
  8. Purification
  9. Crystallization
  10. Filtration and washing
  11. Controlled drying
  12. Particle-size control, where required
  13. Final analytical testing
  14. GMP-compliant packaging

Quality Control Testing

Typical Netupitant API testing may include:

  • Identification by IR
  • HPLC identification
  • Assay by HPLC
  • Related substances by HPLC
  • Specified impurities
  • Genotoxic impurities, where applicable
  • Residual solvents by GC
  • Water content by Karl Fischer
  • Heavy metals / elemental impurities
  • Sulfated ash
  • Particle-size distribution
  • Stability testing

The EMA assessment report specifically confirms that the Netupitant active-substance specification includes IR/HPLC identification, HPLC assay, HPLC impurities, residual solvents, water, heavy metals, sulfated ash and particle-size distribution.

Storage

Store Netupitant API in a tightly closed container under controlled pharmaceutical storage conditions, protected from excessive moisture, heat and direct light.

Final commercial storage conditions should be based on validated stability data and the applicable API specification.

Detailed Specifications

Parameter Specification
Appearance White crystalline powder or crystals
Identification IR & HPLC compliant
Assay (HPLC) 98.0% – 102.0%
Loss on Drying NMT 1.0%
Residue on Ignition NMT 0.5%
Individual Impurity NMT 0.5%
Total Impurities ≤ 1.5%
Water Content NMT 1.0%
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