Neostigmine Methylsulfate API Manufacturer in India

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Neostigmine Methylsulfate API

Neostigmine Methylsulfate is a synthetic reversible acetylcholinesterase inhibitor and cholinergic pharmaceutical API. It increases the availability of acetylcholine by inhibiting its enzymatic breakdown and thereby enhances cholinergic transmission.

Neostigmine Methylsulfate is an important pharmaceutical form of neostigmine used in formulations associated with neuromuscular transmission, reversal of non-depolarizing neuromuscular blockade and other cholinergic applications.

Neostigmine Methylsulfate API Manufacturer in India

Neostigmine Methylsulfate is a well-characterized anticholinesterase pharmaceutical API used in pharmaceutical formulation development, manufacturing, analytical testing and research involving cholinergic and neuromuscular pharmacology.

The API is chemically distinct from Neostigmine Bromide. Neostigmine Methylsulfate has the molecular formula C₁₃H₂₂N₂O₆S and molecular weight 334.39 g/mol.

Chemical Information

CAS Number: 51-60-5

Molecular Formula: C₁₃H₂₂N₂O₆S

Molecular Weight: 334.39 g/mol

Chemical Name: 3-[(Dimethylcarbamoyl)oxy]-N,N,N-trimethylbenzenaminium methyl sulfate

Drug Class: Cholinesterase Inhibitor

Therapeutic Class: Anticholinesterase / Cholinergic Agent

Therapeutic Area: Neurology / Anesthesiology

Molecule Type: Synthetic Small Molecule

Synonyms: Neostigmine Methylsulfate, Neostigmine Methylsulphate, Neostigmine Methosulfate

USP and the International Pharmacopoeia identify the substance as CAS 51-60-5 with molecular formula C₁₃H₂₂N₂O₆S and molecular weight approximately 334.4 g/mol.

Mechanism of Action

Neostigmine Methylsulfate acts as a reversible acetylcholinesterase inhibitor.

Its pharmacological activity includes:

  • Reversible inhibition of acetylcholinesterase
  • Reduction of acetylcholine breakdown
  • Increased acetylcholine availability
  • Enhancement of cholinergic neurotransmission
  • Improvement of neuromuscular transmission
  • Increased skeletal muscle response
  • Increased parasympathetic activity

Because neostigmine is a quaternary ammonium compound, its penetration into the central nervous system is limited.

Pharmaceutical Applications

Neostigmine Methylsulfate API is relevant to:

  • Neuromuscular blockade reversal formulations
  • Anesthesia-related pharmaceutical preparations
  • Cholinergic drug formulations
  • Myasthenia gravis-related pharmaceutical applications
  • Neuromuscular pharmacology research
  • Acetylcholinesterase inhibitor research
  • Pharmaceutical formulation development
  • Pharmaceutical API manufacturing
  • Analytical quality control
  • Cholinergic drug development

Neuromuscular Applications

Neostigmine Methylsulfate increases acetylcholine concentration at the neuromuscular junction by inhibiting acetylcholinesterase.

This pharmacological action enhances neuromuscular transmission and makes the compound particularly relevant to pharmaceutical preparations used for the reversal of non-depolarizing neuromuscular blockade.

Cholinesterase Inhibition

Neostigmine Methylsulfate belongs to the reversible cholinesterase inhibitor class.

By reducing enzymatic degradation of acetylcholine, it enhances the action of acetylcholine at cholinergic receptors. This mechanism is central to its pharmacological applications in neuromuscular and parasympathetic systems.

Physical Characteristics

Neostigmine Methylsulfate is described as a white crystalline powder and is hygroscopic.

It is very soluble in water and freely soluble in ethanol. The International Pharmacopoeia also identifies it as a white crystalline powder and specifies storage in a tightly closed container protected from light.

Manufacturing Process

A controlled Neostigmine Methylsulfate API manufacturing process may involve:

  1. Qualification of starting materials
  2. Preparation of the substituted aromatic intermediate
  3. Formation of the dimethylcarbamate functionality
  4. Controlled quaternization of the tertiary amine
  5. Formation of the methyl sulfate salt
  6. Reaction monitoring
  7. Purification
  8. Crystallization
  9. Filtration and washing
  10. Controlled drying
  11. Milling, where required
  12. Final analytical testing
  13. GMP-compliant packaging

Quality Control Testing

Typical Neostigmine Methylsulfate API testing may include:

  • Identification by IR
  • Chromatographic identification
  • Assay
  • Related substances
  • Dimethylaminophenol-related impurity
  • Chloride
  • Sulfate ion
  • Loss on drying
  • Residue on ignition
  • pH
  • Melting range
  • Appearance of solution
  • Residual solvents
  • Elemental impurities
  • Stability testing

The USP monograph includes identification and assay, while the Japanese Pharmacopoeia additionally specifies pH, melting point, loss on drying and residue on ignition.

Storage

Store Neostigmine Methylsulfate API in a tightly closed container protected from light and moisture.

The International Pharmacopoeia specifically recommends storage in a tightly closed container protected from light.

Detailed Specifications

Parameter Specification
Appearance White crystalline powder or crystals
Identification IR & HPLC compliant
Assay (HPLC) 98.0% – 102.0%
Loss on Drying NMT 1.0%
Residue on Ignition NMT 0.1%
pH (1% Solution) 3.0 – 5.0
Individual Impurity NMT 0.1%
Total Impurities NMT 1.0%
Water Content NMT 1.0%
Melting Point 145 – 149°C
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